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Chiral Ag-atropisomeric ligand species were studied in solution at different temperatures by 31 P-NMR spectroscopy. The analysis and understanding of key parameters in Ag-BINAP complexes were considered in the context… Click to show full abstract
Chiral Ag-atropisomeric ligand species were studied in solution at different temperatures by 31 P-NMR spectroscopy. The analysis and understanding of key parameters in Ag-BINAP complexes were considered in the context of an enantioselective transformation. An efficient silver-catalyzed intramolecular [4+2] cycloaddition reaction of amide-1,6-enyne provided an enantiomerically enriched tricyclic compound using simple reagents and under mild reaction conditions.
Keywords:
chiral binap;
analysis activity;
nmr analysis;
activity chiral;
phosphorous nmr;
analysis
Journal Title: ChemPlusChem
Year Published: 2022
Link to full text (if available)
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Journal Title: ChemPlusChem
Year Published: 2022
Link to full text (if available)
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recommendations!