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Photochemical Carboxylation of Activated C(sp3 )-H Bonds with CO2.

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From ugly duckling to beautiful C1: Although CO2 may represent an ideal C1 source, it is challenging to use it as a raw material and direct carboxylation with CO2 has… Click to show full abstract

From ugly duckling to beautiful C1: Although CO2 may represent an ideal C1 source, it is challenging to use it as a raw material and direct carboxylation with CO2 has mainly been confined to highly reactive species. However, recent significant breakthroughs have been made in photochemical carboxylation of challenging, un-acidic, C(sp3 )-H bonds, including benzylic, allylic and amine C-H bonds.

Keywords: bonds co2; photochemical carboxylation; sp3 bonds; activated sp3; carboxylation; carboxylation activated

Journal Title: ChemSusChem
Year Published: 2017

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