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Encapsulation of cobalt oxide into metal-organic frameworks for an improved photocatalytic CO2 reduction.

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The increased emission of CO 2 has negative impacts on environment. Among the strategies, photocatalytic reduction is promising to convert the CO 2 into chemicals. In this report, CoO x… Click to show full abstract

The increased emission of CO 2 has negative impacts on environment. Among the strategies, photocatalytic reduction is promising to convert the CO 2 into chemicals. In this report, CoO x nanoparticles are loaded in the channels of MIL-101(Cr), a kind of metal organic frameworks (MOF), to construct a novel CoO x /MIL-101(Cr) system to facilitate CO 2 photoreduction. Under the optimal conditions, the CoO x /MIL-101(Cr) has showed a significantly enhanced performance for photocatalytic CO 2 reduction compared with bare CoO x and MIL-101(Cr). Our findings provide a pathway for a rational design of efficient MOF system for the photocatalytic reduction of CO 2 .

Keywords: reduction; metal organic; photocatalytic reduction; organic frameworks; mil 101

Journal Title: ChemSusChem
Year Published: 2020

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