Dual-ion batteries (DIBs) exhibit a distinct set of performance advantages and disadvantages due to their unique storage mechanism. However, the current cyclability/energy density tradeoffs of anion storage paired with the intrinsic… Click to show full abstract
Dual-ion batteries (DIBs) exhibit a distinct set of performance advantages and disadvantages due to their unique storage mechanism. However, the current cyclability/energy density tradeoffs of anion storage paired with the intrinsic required electrolyte loadings of conventional DIBs preclude their widespread adoption as an alternative to lithium-ion batteries (LIBs). Despite this, their reduced desolvation penalty and low-cost electrode materials may warrant their employment for low-temperature and/or grid storage applications. To expand beyond these applications, we also discuss the prospects of solid salt storage and halogen intercalation-conversion as viable methods to increase DIB energy densities to a level on-par with LIBs. This perspective examines the fundamental limitations of conventional DIBs, proposes technology spaces where they can make meaningful impact over LIBs, and outlines potential strategies to improve cell-level energy densities necessary for the widespread adoption of DIBs.
               
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