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A NaOtBu-O2-mediated oxidative dehomologation of homoallylic alcohols into structurally different carboxylic acids through direct oxidative cleavage of either the C(sp2)-C(sp2) or C(sp3)-C(sp3) bond utilizing enolate chemistry was demonstrated. Furthermore, under… Click to show full abstract
A NaOtBu-O2-mediated oxidative dehomologation of homoallylic alcohols into structurally different carboxylic acids through direct oxidative cleavage of either the C(sp2)-C(sp2) or C(sp3)-C(sp3) bond utilizing enolate chemistry was demonstrated. Furthermore, under transition-metal-free conditions, this protocol has been applied to convert terpene as biomass feedstock into value-added chemicals.
Keywords:
metal free;
transition metal;
value added;
added chemicals;
oxidative cleavage
Journal Title: ChemSusChem
Year Published: 2023
Link to full text (if available)
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Journal Title: ChemSusChem
Year Published: 2023
Link to full text (if available)
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recommendations!