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We report studies concerning the selective mono-functionalization of 1,1,3,3-tetramethyldisiloxane (TMDSO) with vinyl-substituted silicon derivatives via the hydrosilylation reaction. Examinations of platinum- and rhodium-based catalysts in the reactions between TMDSO and… Click to show full abstract
We report studies concerning the selective mono-functionalization of 1,1,3,3-tetramethyldisiloxane (TMDSO) with vinyl-substituted silicon derivatives via the hydrosilylation reaction. Examinations of platinum- and rhodium-based catalysts in the reactions between TMDSO and exemplary vinyl-containing silicon derivatives have enabled appointing the most efficient catalyst, whose application leads to selective partial functionalization of the disiloxane reagent and simultaneous formation of only β-regioisomers.
Journal Title: European Journal of Inorganic Chemistry
Year Published: 2017
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