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Reinvestigation of Dilacunary 19-Tungsto-2-Arsenate(III) [AsIII2W19O67(H2O)]14- Including 183W NMR Solution Study

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We have reinvestigated the dilacunary 19-tungsto-2-arsenate(III) [AsIII2W19O67(H2O)]14- (1), resulting in the mixed potassium-sodium salt K8Na6[AsIII2W19O67(H2O)]·28H2O (KNa-1), which was structurally characterized in the solid state by single-crystal XRD, IR, TGA, and… Click to show full abstract

We have reinvestigated the dilacunary 19-tungsto-2-arsenate(III) [AsIII2W19O67(H2O)]14- (1), resulting in the mixed potassium-sodium salt K8Na6[AsIII2W19O67(H2O)]·28H2O (KNa-1), which was structurally characterized in the solid state by single-crystal XRD, IR, TGA, and elemental analysis, as well as in aqueous solution by 183W NMR for the first time.

Keywords: tungsto arsenate; dilacunary tungsto; iii asiii2w19o67; h2o; asiii2w19o67 h2o; arsenate iii

Journal Title: European Journal of Inorganic Chemistry
Year Published: 2017

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