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Synthesis and Reactivity of Thiolate‐Bridged NiIIMI Heterodinuclear Complexes (M = Rh, Ir) with an S‐Bidentate NiP2S2 Metalloligand

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Invited for the cover of this issue is the group of Tomoaki Tanase at Nara Women's University, Japan. The cover image shows the transformation of a low-valent dithiolate-bridged heterodinuclear complex… Click to show full abstract

Invited for the cover of this issue is the group of Tomoaki Tanase at Nara Women's University, Japan. The cover image shows the transformation of a low-valent dithiolate-bridged heterodinuclear complex into two different types of hydride silyl complexes by treatment with hydrosilanes, where the hydride ligands are stabilized by semibridging between two metal centers of a “dimetal butterfly”.

Keywords: thiolate bridged; niiimi heterodinuclear; heterodinuclear complexes; reactivity thiolate; synthesis reactivity; bridged niiimi

Journal Title: European Journal of Inorganic Chemistry
Year Published: 2017

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