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Reactivity of Woollins' Reagent toward 2-En-1-imines (Schiff Bases): A Facile Approach to Synthesize New Selenium-Phosphorus-Nitrogen Heterocycles

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Woollins’ Reagent serves as a reductive cycloaddition reagent, reacting with 2-en-1-imines containing a conjugated C=C bond group (Schiff bases) leading to a series of four-, five-, sixmembered 1,2-azaphospholidines incorporating one… Click to show full abstract

Woollins’ Reagent serves as a reductive cycloaddition reagent, reacting with 2-en-1-imines containing a conjugated C=C bond group (Schiff bases) leading to a series of four-, five-, sixmembered 1,2-azaphospholidines incorporating one or two N-P=Se linkages. Ten single crystal X-ray structures confirming the formation of these small N-P-Se heterocycles are reported.

Keywords: schiff bases; woollins reagent; imines schiff; toward imines; reactivity woollins; reagent toward

Journal Title: European Journal of Inorganic Chemistry
Year Published: 2019

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