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Syntheses and Characterizations of Naphtho‐rhenafuran Complexes with S0 and T0 States

Reactions of o‐alkyl naphthol compounds with ReCl3(PMePh2)3 produced naphtho‐rhenafuran complexes, which adapted different ground states (singlet S0 and triplet T0). These polycyclic structures have been characterized experimentally and theoretically. Their… Click to show full abstract

Reactions of o‐alkyl naphthol compounds with ReCl3(PMePh2)3 produced naphtho‐rhenafuran complexes, which adapted different ground states (singlet S0 and triplet T0). These polycyclic structures have been characterized experimentally and theoretically. Their electronic behaviors have been studied by UV‐Vis absorption and DFT calculations.

Keywords: rhenafuran complexes; naphtho rhenafuran; complexes states; characterizations naphtho; syntheses characterizations

Journal Title: European Journal of Inorganic Chemistry
Year Published: 2024

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