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Supramolecular cavitands that contain inwardly directed functional groups have yielded specialized transformations and trapping of reactive intermediates. A recently reported 3-wall Au cavitand provides exciting opportunities for supramolecular catalysis. In… Click to show full abstract
Supramolecular cavitands that contain inwardly directed functional groups have yielded specialized transformations and trapping of reactive intermediates. A recently reported 3-wall Au cavitand provides exciting opportunities for supramolecular catalysis. In this study, a variety of substituted γ-alkynoic acids were reacted to give lactones. The interaction of peripheral “R” groups revealed differential catalyst behavior.
Keywords:
acid cyclizations;
alkyne acid;
cavitand catalyzed;
chemistry;
catalyzed alkyne
Journal Title: European Journal of Organic Chemistry
Year Published: 2019
Link to full text (if available)
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Journal Title: European Journal of Organic Chemistry
Year Published: 2019
Link to full text (if available)
Share on Social Media: Sign Up to like & get
recommendations!