A variety of N‐acylsulfenamides are produced by the electrochemically enabled cross‐coupling of readily available feedstocks under standard conditions. This protocol is practical and has wide substrate scope with good reaction… Click to show full abstract
A variety of N‐acylsulfenamides are produced by the electrochemically enabled cross‐coupling of readily available feedstocks under standard conditions. This protocol is practical and has wide substrate scope with good reaction efficiency (38 examples, up to 97 % yield). A possible free radical mechanism is preliminarily demonstrated.
               
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