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Green Light Triggered Radical Annulation for the Synthesis of Indenone by Metal‐Free Photocatalysis

Low‐energy light, endowing with excellent characteristics of lower energy, fewer side reactions, more abundance in solar light. The scenario has been developed for the fabrication of indenone through a low‐energy… Click to show full abstract

Low‐energy light, endowing with excellent characteristics of lower energy, fewer side reactions, more abundance in solar light. The scenario has been developed for the fabrication of indenone through a low‐energy green light driven radical annulation reaction between α‐keto acids and internal alkynes using Rhodamine 6G as photocatalyst. Various kinds of substrates are suitable for this methodology, affording the corresponding indenones in a greener and efficient manner.

Keywords: radical annulation; light; green light; indenone; light triggered

Journal Title: European Journal of Organic Chemistry
Year Published: 2024

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