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Supergene sulphuric acid speleogenesis and the origin of hypogene caves: evidence from the Northern Pennines, UK

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The maze caves of the Northern Pennines are rectilinear joint‐controlled networks of predominantly tall vertical rifts developed on one level towards the top of a ~20 m thick limestone bed; they… Click to show full abstract

The maze caves of the Northern Pennines are rectilinear joint‐controlled networks of predominantly tall vertical rifts developed on one level towards the top of a ~20 m thick limestone bed; they were all intersected by underground mines and have no relationship to the present landscape. Passage walls commonly have large, non‐directional scallops; speleothems are uncommon. The caves were previously identified as hypogene in origin, i.e. formed by groundwater ascending from depth, but reassessment of their origin using published data shows that they lack diagnostic hypogene features (rising wall channels, ceiling channels, ceiling cupolas and dome‐pits), and the low permeability strata above and below the limestone bed greatly restrict vertical groundwater flow through the caves. Instead the maze caves were dissolved by the sulphuric acid released by oxidation of iron sulphides (and perhaps chalcopyrite) in the mineralized veins adjacent to all these caves; passage sizes decrease away from the veins and gypsum encrusts the walls of one cave. The maze caves were not formed by vertical groundwater flow, and dissolution was focussed in a relatively small area of limestone beneath an impermeable confining layer. The caves began to form when river incision due to the probably Late Cenozoic uplift of northern England exposed the iron sulphides to weathering and oxidation.

Keywords: northern pennines; sulphuric acid; supergene sulphuric; hypogene; origin; maze caves

Journal Title: Earth Surface Processes and Landforms
Year Published: 2020

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