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Terminal alkynes having a bulky substituent dehydrogenatively couple with unactivated terminal alkenes with catalysis of palladium. The terminal sp carbon forms a bond with the internal sp2 carbon of the… Click to show full abstract
Terminal alkynes having a bulky substituent dehydrogenatively couple with unactivated terminal alkenes with catalysis of palladium. The terminal sp carbon forms a bond with the internal sp2 carbon of the alkene regioselectively to produce branched, conjugated 1,3-enynes with wide functional group tolerance.
Keywords:
catalyzed dehydrogenative;
reaction terminal;
coupling reaction;
terminal alkynes;
palladium catalyzed;
dehydrogenative coupling
Journal Title: Journal of The Chinese Chemical Society
Year Published: 2018
Link to full text (if available)
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Journal Title: Journal of The Chinese Chemical Society
Year Published: 2018
Link to full text (if available)
Share on Social Media: Sign Up to like & get
recommendations!