Agricultural losses of dissolved reactive phosphorus (DRP) emanate from both "old P" from historic P applications, "old P", and recently applied fertilizer, "new P", and understanding the relative contributions of… Click to show full abstract
Agricultural losses of dissolved reactive phosphorus (DRP) emanate from both "old P" from historic P applications, "old P", and recently applied fertilizer, "new P", and understanding the relative contributions of these sources is important for mitigating DRP losses from agriculture. This study provides a proof-of-concept for resolving new versus old P source contributions to DRP losses in subsurface tile drainage using edge-of-field water quality data and management records from eight fields in Ohio. Weighted regressions on discharge and season (WRDS) were fitted using data from periods without P fertilizer applications, then employed to predict DRP losses in tile drainage during new P loss risk periods (default length of 90 d) following fertilizer applications. Differences between observed and predicted DRP concentrations during the new P loss risk period were attributed to the new P source. Remaining losses were attributed to the old soil P source. The WRDS model performance was modest (modified Kling-Gupta efficiency ranged from -0.074 to 0.484). New P sources contributed between 0 and 17% of overall DRP losses (average of 7%), with old soil P contributing 83 to 100%. Individual P fertilizer applications were associated with new DRP losses up to 192 g P ha-1 . Increasing the length of the risk period for new P losses up to 180 d after fertilizer application marginally increased the estimated contribution of the new P source. The WRDS-based analysis provides a novel approach for resolving the contributions of new and old sources to edge-of-field DRP losses. This article is protected by copyright. All rights reserved.
               
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