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Tip-enhanced Raman mapping of single-walled carbon nanotube networks in conductive composite materials

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Identifying and characterizing the structural integrity of single-walled carbon nanotubes (SWCNTs) that are fully embedded in a polymer matrix without causing any damage to them is a difficult task to… Click to show full abstract

Identifying and characterizing the structural integrity of single-walled carbon nanotubes (SWCNTs) that are fully embedded in a polymer matrix without causing any damage to them is a difficult task to achieve for bulk samples. Using tip-enhanced Raman spectroscopy, the surface of a polymer-embedded conductive network of SWCNTs was mapped underneath a thin layer of pure polymer. The technique was also used to detect tube-breaking within the composite sample caused by mechanical stress, beyond the ‘visual’ capabilities of scanning electron microscopy techniques. Results show that tip-enhanced Raman mapping can be used to successfully identify and characterize SWCNTs even underneath a layer of polymer. Copyright © 2016 John Wiley & Sons, Ltd.

Keywords: raman mapping; enhanced raman; tip enhanced; walled carbon; single walled; spectroscopy

Journal Title: Journal of Raman Spectroscopy
Year Published: 2017

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