In this study, a new covalent organic framework, consisting of tetra(4-aminophenyl)porphyrin and tris(4-formyl phenyl)amine, was layer-by-layer immobilized on stainless-steel wire as a coating for microextraction. The fabrication process was easy… Click to show full abstract
In this study, a new covalent organic framework, consisting of tetra(4-aminophenyl)porphyrin and tris(4-formyl phenyl)amine, was layer-by-layer immobilized on stainless-steel wire as a coating for microextraction. The fabrication process was easy and controllable under mild conditions. The as-grown extracted fiber was applied to extract polycyclic aromatic hydrocarbons in aqueous solution via head-space solid-phase microextraction. Furthermore, it was analyzed by gas chromatography with a flame ionization detector. A wide linear range (0.1-50 μg L-1 ), low limits of detection (0.006-0.024 μg L-1 , signal-to-noise ratio = 3), good repeatability (intra-fiber, n = 6, 3.1%-8.50%), and reproducibility (fiber to fiber; n = 3, 5.79%-9.98%), expressed as relative standard deviations, demonstrating the applicability of the newly developed coating. This new material was successfully utilized in real sample extraction with a satisfactory result. Potential parameters affecting the extraction efficiency, including extraction temperature and extraction time, salt concentration, agitation speed, sample volume, desorption temperature, and time, were also optimized and discussed. This article is protected by copyright. All rights reserved.
               
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