LAUSR

A novel molecularly imprinted polymer based on magnetic multi-walled carbon nanotubes was fabricated and applied for selective dispersive micro-solid phase extraction of fenitrothion prior its determination by ion mobility spectrometry. The composite was synthesized using magnetic multi-walled carbon nanotubes as the support. Methacrylic acid was used as the functional monomer, fenitrothion as the template, ethylene glycol dimethacrylate as the cross-linker and 2,2-azoisobutyronitrile as the initiator. The resultant polymer was characterized by Fourier transform infrared spectroscopy, X-ray diffraction, field emission scanning electron microscopy, Brunauer-Emmet-Teller analysis, thermogravimetric analysis and vibrating sample magnetometer techniques. Experimental factors affecting the extraction efficiency such as pH and amount of sorbent were evaluated. Under optimum experimental conditions, the developed method displayed the linear range of 5-220 μg L-1 with a detection limit (LOD) of 1.3 μg L-1 . The intra and inter-day relative standard deviations (RSD%) for determination of fenitrothion were 3.6 and 4.7% (n = 6), respectively. Ultimately, the proposed method was used to monitoring of trace amounts of fenitrothion in fruit,vegetable and water samples. This article is protected by copyright. All rights reserved.