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Herein, the synthesis of a novel nitroxide-mediated polymerization (NMP) initiator bearing a photolabile ortho-nitrobenzyl (oNB) group allowing surface-initiated NMP preparation of well-defined photoresponsive polystyrene grafted on silica nanoparticles is described.… Click to show full abstract
Herein, the synthesis of a novel nitroxide-mediated polymerization (NMP) initiator bearing a photolabile ortho-nitrobenzyl (oNB) group allowing surface-initiated NMP preparation of well-defined photoresponsive polystyrene grafted on silica nanoparticles is described. The photocleavable and photoresponsive properties of the prepared materials are demonstrated using small angle X-ray scattering (SAXS) characterization.
Keywords:
well defined;
grafted silica;
mediated polymerization;
nitroxide mediated;
polystyrene grafted;
polymerization nmp
Journal Title: Macromolecular rapid communications
Year Published: 2021
Link to full text (if available)
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Journal Title: Macromolecular rapid communications
Year Published: 2021
Link to full text (if available)
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recommendations!