LAUSR

We report a simple preparation of inorganic reinforced poly(ionic liquid) (PIL) microcapsules by combining dispersion polymerization and confined cooling-assisted phase separation self-assembly. Silane coupling agent-modified PIL microbeads were first prepared by dispersion polymerization. Then, the microbeads were dissolved in a mixed solvent composed of good solvent and non-solvent to form hollow SiOx microcapsules at a relatively high temperature. Finally, the solution was cooled to induce the nucleation and growth of dissolved PIL chains on the inner and outer surface of hollow SiOx microcapsules to form inorganic reinforced microcapsules with asymmetric PIL/SiOx /PIL sandwich-like shell. The morphology of microcapsules can be controlled by adjusting PIL concentration and cooling rate. The inorganic reinforced microcapsules show enhanced suspended stability and electro-responsive characteristic when used as the dispersed phase of smart suspensions. This article is protected by copyright. All rights reserved.