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Versatile Route for Multifunctional Aerogels Including Flaxseed Mucilage and Nanocrystals.

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Preparation of low density monolithic and free-standing organic-inorganic hybrid aerogels of various properties is demonstrated using green chemistry from a biosafe natural source (flaxseed mucilage) and freeze-casting and subsequent freeze… Click to show full abstract

Preparation of low density monolithic and free-standing organic-inorganic hybrid aerogels of various properties is demonstrated using green chemistry from a biosafe natural source (flaxseed mucilage) and freeze-casting and subsequent freeze drying. Bio-aerogels, luminescent aerogels and magneto-responsive aerogels were obtained by combination of the flaxseed mucilage with different types of nanoparticles. Moreover, the aerogels are investigated as possible drug release system using curcumin as a model. Various characterization techniques like thermogravimetric analysis, nitrogen physisorption, electron microscopy, UV/Vis absorption and emission spectroscopy, bulk density and mechanical measurements as well as in vitro release profile measurements are employed to investigate the obtained materials. The flaxseed-inspired organic-inorganic hybrid aerogels exhibit ultra-low densities of as low as 5.6 mg/cm3 for 0.5% (w/v) mucilage polymer, a specific surface area of 4 to 20 m2 /g, high oil absorption capacity (23 g/g) and prominent compressibility. The natural biopolymer technique leads to low cost and biocompatible functional lightweight materials with tunable properties (physicochemical and mechanical) and significant potential for applications as supporting or stimuli responsive materials, carriers, reactors, microwave, and electromagnetic radiation protective (absorbing) material as well as in drug delivery and oil absorption. This article is protected by copyright. All rights reserved.

Keywords: aerogels including; mucilage; multifunctional aerogels; flaxseed mucilage; route multifunctional; versatile route

Journal Title: Macromolecular rapid communications
Year Published: 2022

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