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We report the synthesis of acrylates with an isocyanurate substituent that show significant volume expansion on radical photo-polymerization. The acrylate consisting of benzyl bisurethane moieties exhibits the largest volume expansion… Click to show full abstract
We report the synthesis of acrylates with an isocyanurate substituent that show significant volume expansion on radical photo-polymerization. The acrylate consisting of benzyl bisurethane moieties exhibits the largest volume expansion among them and contributes to restrict volume change upon its radical photo-copolymerization with a diacrylate exhibiting volume shrinkage. Furthermore, it is revealed that the correlation between the volume change behavior and the polymer structure through the radical photo-polymerization of the isocyanurate core-based diacrylate with benzyl bisurethane moieties under various concentration conditions. This article is protected by copyright. All rights reserved.
Journal Title: Macromolecular rapid communications
Year Published: 2022
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