LAUSR

For utilizing the organic solar cells for commercial applications, reducing the overall cost of the photo absorbent materials is also very crucial, along with the realization of high power conversion efficiency (PCE) and excellent stability. Herein, we tried to address such challenge by synergistically controlling the amount of fluorine (F)-substituents (n = 2, 4) on easily scalable, low-cost wide-bandgap molecular design involving alternate fluorinated-thienyl benzodithiophene donor and 2,5-difluoro benzene (2FBn) or 2,3,5,6 tetrafluorobenzene (4FBn) to form two new polymer donors PBDT-2FBn and PBDT-4FBn, respectively. As expected, sequential fluorination causes lowering of the frontier energy levels and planarization of polymer backbone via F···S and C-H···F noncovalent molecular locks, which results in more pronounced molecular packing and enhanced crystallinity from PBDT-2FBn to PBDT-4FBn. By mixing with IT-4F acceptor, PBDT-2FBn:IT-4F-based blend demonstrated favorable molecular orientation with shorter π-π stacking distance, higher carrier mobilities with good trade-off ratio and desirable nanoscale morphology, hence delivered good PCE of 9.3% than PBDT-2FBn:IT-4F counterpart (8.6%). Furthermore, pairing PBDT-2FBn with BTP-BO-4Cl acceptor further improved absorption range and promoted privileged morphology with ideal domain sizes for efficient exciton dissociation and charge transport, resulting in further improvement of PCE to 10.2% with remarkably low energy loss of 0.46 eV, which is seldomly reported in NF-OSCs. Consequently, this study provides valuable guidelines for designing efficient and low-cost polymer donors for organic solar cell applications. This article is protected by copyright. All rights reserved.