LAUSR

The past one hundred years witness the great development of polymer science. The advancement of polymer science is closely related with the developing of characterization techniques and methods, from viscometry in molecular weight determination to advanced techniques including differential scanning calorimetry, nuclear magnetic resonance and scanning electron microscopy. However, these techniques are normally constrained to tedious sample preparation, high cost, harsh experimental condition, or ex-situ characterization. Fluorescence technology has the merits of high sensitivity and direct visualization. Contrary to conventional aggregation-causing quenching fluorophores, those dyes with aggregation-induced emission characteristic show high emission efficiency in aggregate states. Based on the restriction of intramolecular motions for AIE properties, the AIE materials are very sensitive to the surrounding microenvironments owing to the twisted propeller-like structures and therefore reveal great potentials in polymer's study. The AIE concept has been successfully used in polymer's study and provides us a deeper understanding on polymer structure and properties. In this review, the applications of AIEgens in polymer science for visualizing polymerization, glass transition, dissolution, crystallization, gelation, self-assembly, phase separation, cracking and self-healing were exemplified and summarized. Lastly, the challenges and perspectives in the study of polymer science using AIEgens are addressed. This article is protected by copyright. All rights reserved.