LAUSR

Single-chain polymer nanoparticles (SCNPs) are soft matter constructed by intrachain crosslink, with promising prospects in detection and catalysis. Herein, the fluorescent core (SCNPs) with aggregation-induced emission (AIE) was prepared, applying for H2 O2 detection through intermolecular heavy-atom effect. In detail, the SCNPs precursors were synthesized by ring-opening copolymerization. Then the SCNPs were prepared by intramolecularly cross-linking via olefin metathesis. Imitating the structure of AIE dots, SCNPs were encapsulated by H2 O2 -responsive polymers. Probably due to the stable secondary structure of SCNPs, the obtained micelles show stable fluorescence performance. Furthermore, as the heavy-atom, tellurium was introduced into the carriers to construct the heavy-atom effect. In this micelle-based system, the SCNPs act as the fluorescent core, and the stimuli-responsive polymer acts as the carrier and the fluorescent switch. The hydrophilicity of the tellurium-containing segment is affected by the concentration of H2 O2 , resulting in a change in the distance from the SCNPs, which ultimately leads to a change in the fluorescence intensity. And tellurium is particularly sensitive to H2 O2 , which can detect low concentrations of H2 O2 . The SCNPs were merged with AIE materials, hoping to explore new probe design. This article is protected by copyright. All rights reserved.