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Morphologically Tunable Supramolecular Rectangular Microsheet and Microsaw Constructed by Hierarchical Self-assembly Based on Hydrogen Bonds.

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Amino acid derivative TDAV as new building blocks for two-dimensional (2D) supramolecular assembly has been designed. Various square and rectangular microsheets are achieved and the aspect ratios are precisely regulated… Click to show full abstract

Amino acid derivative TDAV as new building blocks for two-dimensional (2D) supramolecular assembly has been designed. Various square and rectangular microsheets are achieved and the aspect ratios are precisely regulated by controlling the polarity of cosolvent or water content. By the introduction of chirality, the novel microsaw is also achieved. It provides a new approach to prepare various kinds of unique supramolecular 2D materials with controllable shapes and sizes for future biological applications. This article is protected by copyright. All rights reserved.

Keywords: microsaw constructed; morphologically tunable; supramolecular rectangular; rectangular microsheet; microsheet microsaw; tunable supramolecular

Journal Title: Macromolecular rapid communications
Year Published: 2022

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