The relativistic HALA effect has been shown to depend on the spatial deformation of the lone electron pairs of a heavy atom, as demonstrated for alkyl and alkene phosphine tellurides.… Click to show full abstract
The relativistic HALA effect has been shown to depend on the spatial deformation of the lone electron pairs of a heavy atom, as demonstrated for alkyl and alkene phosphine tellurides. It was found that HALA effect on phosphorous nuclear magnetic resonance shielding constant is strongly dependent on the spatial arrangements of light substituents on phosphorus, resulting in the deformation of the lone electron pairs of tellurium.
               
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