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Suppressing Self-Discharge and Shuttle Effect of Lithium-Sulfur Batteries with V2 O5 -Decorated Carbon Nanofiber Interlayer.

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V2 O5 decorated carbon nanofibers (CNFs) are prepared and used as a multifunctional interlayer for a lithium-sulfur (Li-S) battery. V2 O5 anchored on CNFs can not only suppress the shuttle… Click to show full abstract

V2 O5 decorated carbon nanofibers (CNFs) are prepared and used as a multifunctional interlayer for a lithium-sulfur (Li-S) battery. V2 O5 anchored on CNFs can not only suppress the shuttle effect of polysulfide by the strong adsorption and redox reaction, but also work as a high-potential dam to restrain the self-discharge behavior in the battery. As a result, Li-S batteries with a high capacity and long cycling life can be stored and rested for a long time without obvious capacity fading.

Keywords: shuttle effect; lithium sulfur; interlayer; self discharge; decorated carbon

Journal Title: Small
Year Published: 2017

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