LAUSR.org creates dashboard-style pages of related content for over 1.5 million academic articles. Sign Up to like articles & get recommendations!

Transition Metal Non-Oxides as Electrocatalysts: Advantages and Challenges.

Photo by viazavier from unsplash

The identification of hydrogen as green fuel in the near future has stirred global realization toward a sustainable outlook and thus boosted extensive research in the field of water electrolysis… Click to show full abstract

The identification of hydrogen as green fuel in the near future has stirred global realization toward a sustainable outlook and thus boosted extensive research in the field of water electrolysis focusing on the hydrogen evolution reaction (HER), oxygen evolution reaction (OER), and oxygen reduction reaction (ORR). A huge class of compounds consisting of transition metal-based nitrides, carbides, chalcogenides, phosphides, and borides, which can be collectively termed transition metal non-oxides (TMNOs), has emerged recently as an efficient class of electrocatalysts in terms of performance and longevity when compared to transition metal oxides (TMOs). Moreover, the superiority of TMNOs over TMOs to effectively catalyze not only OERs but also HERs and ORRs renders bifunctionality and even trifunctionality in some cases and therefore can replace conventional noble metal electrocatalysts. In this review, the crystal structure and phases of different classes of nanostructured TMNOs are extensively discussed, focusing on recent advances in design strategies by various regulatory synthetic routes, and hence diversified properties of TMNOs are identified to serve as next-generation bi/trifunctional electrocatalysts. The challenges and future perspectives of materials in the field of energy conversion and storage aiding toward a better hydrogen economy are also discussed in this review.

Keywords: metal; transition metal; metal non; non oxides

Journal Title: Small
Year Published: 2022

Link to full text (if available)


Share on Social Media:                               Sign Up to like & get
recommendations!

Related content

More Information              News              Social Media              Video              Recommended



                Click one of the above tabs to view related content.