LAUSR

Solution‐processing approaches are widely used for controlling the aggregation structure of organic semiconductors because they are fast, efficient, and have strong practicability. Effective regulation of the aggregation structure of molecules to achieve highly ordered molecular stacking is key to realizing effective carrier transport and high‐performance devices. Numerous studies have achieved highly aligned organic semiconductors using different solution‐processing approaches. This article provides a detailed review of the prevalent solution‐processing technologies and emerging methods developed over the past few years for the alignment of organic semiconducting materials. These technologies and methods are classified according to the processing principle. This review focuses on the principles of different experimental techniques, improvements upon the conventional methods, and state‐of‐the‐art performance of resulting devices. In addition, a brief discussion of the characteristics and development prospects of various methods is presented.