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Re‐Determination of the Crystal Structure of MIL‐91(Al)

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The structure of one of the first permanently porous metal phosphonates, MIL‐91(Al) was re‐determined using high resolution synchrotron powder X‐ray diffraction data. The new model is in a lower symmetry… Click to show full abstract

The structure of one of the first permanently porous metal phosphonates, MIL‐91(Al) was re‐determined using high resolution synchrotron powder X‐ray diffraction data. The new model is in a lower symmetry space group, with no disordered ligands in the structure, whilst remaining otherwise consistent with the reported compound. New milder synthetic conditions were also developed.

Keywords: structure mil; determination crystal; crystal structure; structure

Journal Title: Zeitschrift Fur Anorganische Und Allgemeine Chemie
Year Published: 2017

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