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NITROGEN HETEROCYCLIC SALTS OF POLYHEDRAL BORANE ANIONS: FROM IONIC LIQUIDS TO ENERGETIC MATERIALS

Synthesis, structure, and physical properties of nitrogen heterocyclic salts of the polyhedral borane anions (closo-decaborate [B 10 H 10 ] 2– , closo-dodecaborate [B 12 H 12 ] 2– ,… Click to show full abstract

Synthesis, structure, and physical properties of nitrogen heterocyclic salts of the polyhedral borane anions (closo-decaborate [B 10 H 10 ] 2– , closo-dodecaborate [B 12 H 12 ] 2– , carba-closo-dodecaborate [CB 11 H 12 ] – , and 3,3'-cobaltabis(1,2-dicarbollide) [3,3'-Co(1,2-C 2 B 9 H 11 ) 2 ] – )  and their derivatives, including their potential application as ionic liquids and energetic materials, are reviewed. Author: Igor B. Sivaev

Keywords: borane anions; heterocyclic salts; salts polyhedral; ionic liquids; polyhedral borane; nitrogen heterocyclic

Journal Title: Chemistry of Heterocyclic Compounds
Year Published: 2017

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