Synthesis and thermal stability of 1,2-oxaphosphetane 2-oxide and 1,2-thiaphosphetane 2-sulfide derivatives are discussed. This microreview covers the available synthetic methods of thermally labile 1,2-oxaphosphetane 2-oxides and 1,2-thiaphosphetane 2-sulfides and their… Click to show full abstract
Synthesis and thermal stability of 1,2-oxaphosphetane 2-oxide and 1,2-thiaphosphetane 2-sulfide derivatives are discussed. This microreview covers the available synthetic methods of thermally labile 1,2-oxaphosphetane 2-oxides and 1,2-thiaphosphetane 2-sulfides and their fragmentation. The synthetic approaches may be classified in four distinct categories: cycloaddition, cyclization, fragmentation, and annulation.
Keywords:
oxides thiaphosphetane;
thiaphosphetane sulfides;
oxaphosphetane oxides;
oxaphosphetane;
labile oxaphosphetane;
thermally labile
Journal Title: Chemistry of Heterocyclic Compounds
Year Published: 2020
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Journal Title: Chemistry of Heterocyclic Compounds
Year Published: 2020
Link to full text (if available)
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recommendations!