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Design and fabrication of cost-effective and sensitive non-enzymatic hydrogen peroxide sensor using Co-doped δ-MnO2 flowers as electrode modifier

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The development of a cost-effective and highly sensitive hydrogen peroxide sensor is of great importance. Electrochemical sensing is considered the most sensitive technique for hydrogen peroxide detection. Herein, we reported… Click to show full abstract

The development of a cost-effective and highly sensitive hydrogen peroxide sensor is of great importance. Electrochemical sensing is considered the most sensitive technique for hydrogen peroxide detection. Herein, we reported a cost-effective and highly sensitive hydrogen peroxide sensor using Co-doped δ-MnO2 (Co@δ-MnO2) flower-modified screen-printed carbon electrode. The δ-MnO2 and Co@δ-MnO2 flowers were synthesized by employing a hydrothermal approach. Advanced techniques such as PXRD, SEM, FTIR, Raman, UV, EDX, BET, and TEM were utilized to confirm the formation of δ-MnO2 and Co-doped δ-MnO2 flowers. The fabricated sensor exhibited an excellent detection limit (0.12 μM) and sensitivity of 5.3 μAμM−1 cm−2. Graphical abstract

Keywords: hydrogen; hydrogen peroxide; peroxide sensor; doped mno2; cost effective

Journal Title: Analytical and Bioanalytical Chemistry
Year Published: 2020

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