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Sound velocities of skiagite–iron–majorite solid solution to 56 GPa probed by nuclear inelastic scattering

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High-pressure experimental data on sound velocities of garnets are used for interpretation of seismological data related to the Earth’s upper mantle and the mantle transition zone. We have carried out… Click to show full abstract

High-pressure experimental data on sound velocities of garnets are used for interpretation of seismological data related to the Earth’s upper mantle and the mantle transition zone. We have carried out a Nuclear Inelastic Scattering study of iron-silicate garnet with skiagite (77 mol%)–iron–majorite composition in a diamond anvil cell up to 56 GPa at room temperature. The determined sound velocities are considerably lower than sound velocities of a number of silicate garnet end-members, such as grossular, pyrope, Mg–majorite, andradite, and almandine. The obtained sound velocities have the following pressure dependencies: Vp [km/s] = 7.43(9) + 0.039(4) × P [GPa] and Vs [km/s] = 3.56(12) + 0.012(6) × P [GPa]. We estimated sound velocities of pure skiagite and khoharite, and conclude that the presence of the iron–majorite component in skiagite strongly decreases Vs. We analysed the influence of Fe3+ on sound velocities of garnet solid solution relevant to the mantle transition zone and consider that it may reduce sound velocities up to 1% relative to compositions with only Fe2+ in the cubic site.

Keywords: nuclear inelastic; sound velocities; inelastic scattering; iron majorite; iron; gpa

Journal Title: Physics and Chemistry of Minerals
Year Published: 2017

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