LAUSR.org creates dashboard-style pages of related content for over 1.5 million academic articles. Sign Up to like articles & get recommendations!

Comments on “Structure of a self-assembled network made of polymeric worm-like micelles” by Wissam Moussa

Photo by mybbor from unsplash

In this paper, W. Moussa investigates the structural and rheological properties of aqueous solutions of a self-assembled comb-like cationic amphiphilic polymer that consists of a polystyrene backbone onto which quaternary… Click to show full abstract

In this paper, W. Moussa investigates the structural and rheological properties of aqueous solutions of a self-assembled comb-like cationic amphiphilic polymer that consists of a polystyrene backbone onto which quaternary ammonium pendant groups bearing octadecyl side chains have been grafted. It is shown that the polymer self-assemble within cylindrical aggregates when dispersed in water leading to the formation of hydrogel at high concentration. These hydrogels do not reach any steady state when heated. Their rheological features are discussed in terms of entanglements of cylindrical micelles. This paper has been submitted without the agreement of the co-authors (Erratum to: Polym. Bull. (2016) 73:2689–2705 doi:10.1007/s00289-016-1615-5) who have not been able to reproduce the results that were reported. They believe that the ageing of the sample upon heating is due to an artifact caused by contamination of the sample. Interested readers are advised to read a thorough rheological study of the same type of polymers where the samples are not contaminated and which has been recently published (Dynamic Mechanical Properties of Networks of Wormlike Micelles Formed by Self-Assembled Comblike Amphiphilic Copolyelectrolytes F Dutertre, L Benyahia, C Chassenieux, T Nicolai—Macromolecules, 2016, doi:10. 1021/acs.macromol.6b01369).

Keywords: network made; comments structure; self assembled; self; assembled network; structure self

Journal Title: Polymer Bulletin
Year Published: 2017

Link to full text (if available)


Share on Social Media:                               Sign Up to like & get
recommendations!

Related content

More Information              News              Social Media              Video              Recommended



                Click one of the above tabs to view related content.