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Kinetics and mechanisms of Zn2+ release from antimicrobial food packaging based on poly (butylene adipate-co-terephthalate) and zinc oxide nanoparticles

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Intended for use in the food packaging field, active PBAT/ZnO bionanocomposite films were successfully prepared by solvent casting and characterized by several techniques. The antibacterial performance of these nanomaterials was… Click to show full abstract

Intended for use in the food packaging field, active PBAT/ZnO bionanocomposite films were successfully prepared by solvent casting and characterized by several techniques. The antibacterial performance of these nanomaterials was evaluated against three bacterial strains ( Staphylococcus aureus , Pseudomonas aeruginosa and Bacillus subtilis ), and a Zn 2+ ions liberation study was also carried out, focusing thus their potential and effectiveness in food packaging industry application. The viability curves of PBAT/ZnO samples against the three bacterial strains showed a considerable decrease in bacteria’s number, confirming therefore the high antibacterial performance of these nanocomposite films, against both of Gram-positive and Gram-negative bacteria, whereas the Zn 2+ release profiles have approved a long-term controlled release during a time period exceeding 45 days. Furthermore, the kinetic modeling of Zn 2+ ions release plots indicates a good fit with Higuchi and Korsmeyer–Peppas models, and describing therefore the combination of three physicochemical phenomena: dissolution, diffusion and degradation, as mechanism inducing thus the controlled Zn 2+ ions release.

Keywords: food packaging; kinetics mechanisms; mechanisms zn2; food; release

Journal Title: Polymer Bulletin
Year Published: 2020

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