LAUSR

The rheological behavior of star-shaped SSBR/silica 60 phr compounds with different filler surface areas was experimentally studied and simulated using constitutive modeling. Rheological behavior was characterized in small amplitude oscillatory shear (SAOS) and stress relaxation after a small step shear. Unfilled SBR and SBR filled with four different silica grades with BET surface areas of 55, 135, 160, and 195 m2/g were used. A clear trend in rheological behavior was observed with surface area. A frequency sweep in the SAOS regime indicated an increase in dynamic properties with surface area. Additionally, linear stress relaxation tests at a strain level of 0.05 showed an increase in relaxation modulus with surface area and the presence of a plateau in the relaxation modulus at large times in compounds containing silica with high surface areas. The Leonov and Simhambhatla-Leonov models, modified to incorporate multimode particle network relaxation, were successfully used to simulate the frequency dependence of the storage modulus and the time evolution of the linear relaxation modulus for all samples. However, simulations of the frequency dependence of the loss modulus showed poor results in comparison with experimental data for the filled compounds.