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The reactions of β-azolyl enamines with azides proceeded under solvent-free conditions in the absence of base at 110°С by one of the possible routes, selectively forming 1,4-disubstituted 1,2,3-triazoles. The proposed… Click to show full abstract
The reactions of β-azolyl enamines with azides proceeded under solvent-free conditions in the absence of base at 110°С by one of the possible routes, selectively forming 1,4-disubstituted 1,2,3-triazoles. The proposed reaction mechanism includes cycloaddition of the starting reagents, leading to 1,2,3-triazoline intermediates, followed by elimination of dimethylamine and the formation of aromatic triazole ring.
Keywords:
azolyl enamines;
synthesis triazoles;
triazoles linked;
enamines azides;
reaction;
linked chains
Journal Title: Chemistry of Heterocyclic Compounds
Year Published: 2018
Link to full text (if available)
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Journal Title: Chemistry of Heterocyclic Compounds
Year Published: 2018
Link to full text (if available)
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recommendations!