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Photochromic difurylethene bisaldehyde as potential building block for [AA] and [AB]2 macrocyclization

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Catalyst- and template-free condensation of photochromic difurylethene bisaldehyde with o-phenylenediamine led to selective formation of macrocyclic Schiff base [AB]2 product. Application of the same difurylethene bisaldehyde in the McMurry reaction… Click to show full abstract

Catalyst- and template-free condensation of photochromic difurylethene bisaldehyde with o-phenylenediamine led to selective formation of macrocyclic Schiff base [AB]2 product. Application of the same difurylethene bisaldehyde in the McMurry reaction resulted in cyclic dimer formation in moderate yield. No linear oligomers were observed in both approaches.

Keywords: photochromic difurylethene; difurylethene; bisaldehyde potential; building block; potential building; difurylethene bisaldehyde

Journal Title: Chemistry of Heterocyclic Compounds
Year Published: 2019

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