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Synthesis of 4,4'-Bis[3-(Fluorodinitromethyl)-1H-1,2,4-triazol-5-Yl]azofurazan

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A three-step method was developed for converting both ethoxycarbonylmethyl groups of 4,4'-bis[3-(ethoxycarbonylmethyl)-1 Н -1,2,4-triazol-5-yl]azofurazan into fluorodinitromethyl groups, enabling the preparation of the target 4,4'-bis[3-(fluorodinitromethyl)-1 Н -1,2,4-triazol-5-yl]azofurazan in 74% overall yield. Click to show full abstract

A three-step method was developed for converting both ethoxycarbonylmethyl groups of 4,4'-bis[3-(ethoxycarbonylmethyl)-1 Н -1,2,4-triazol-5-yl]azofurazan into fluorodinitromethyl groups, enabling the preparation of the target 4,4'-bis[3-(fluorodinitromethyl)-1 Н -1,2,4-triazol-5-yl]azofurazan in 74% overall yield.

Keywords: bis fluorodinitromethyl; triazol; triazol azofurazan; fluorodinitromethyl triazol

Journal Title: Chemistry of Heterocyclic Compounds
Year Published: 2020

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