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Conversion of acetyl cedrene (2) to its follower (3) using acetic anhydride and polyphosphoric acid involves a multi-step cationic molecular rearrangement, which is consistent with deuteriation and 1-13C labeling studies… Click to show full abstract
Conversion of acetyl cedrene (2) to its follower (3) using acetic anhydride and polyphosphoric acid involves a multi-step cationic molecular rearrangement, which is consistent with deuteriation and 1-13C labeling studies of acetyl cedrene. The key step involves cyclopropylcarbinyl cation-cyclopropylcarbinyl cation rearrangement.
Keywords:
acetyl cedrene;
step;
rearrangement;
follower;
multi step
Journal Title: Chemistry of Natural Compounds
Year Published: 2017
Link to full text (if available)
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Journal Title: Chemistry of Natural Compounds
Year Published: 2017
Link to full text (if available)
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recommendations!