The Seebeck coefficient (SC) or thermopower of an organic material may be modeled by using an energy-dependent Gaussian density of states and an energy-dependent diffusivity. Once these have been formulated… Click to show full abstract
The Seebeck coefficient (SC) or thermopower of an organic material may be modeled by using an energy-dependent Gaussian density of states and an energy-dependent diffusivity. Once these have been formulated or parameterized from experimental evidence, the Kubo–Greenwood integral can then be employed in order to analytically evaluate the Seebeck coefficient. The main purpose is to show that a complete analytical formula for the Seebeck coefficient may be obtained for an organic material without recourse to any analytical approximations, asymptotic formulations, or numerical methods. The method developed in this article should not be used to supplant other methods, but to supplement them. In fact, the main advantage for having an analytical formula for the SC is for its use in parametric studies. In order to illustrate the analytical method developed in this article, the author has chosen, for simplicity, a constant diffusivity over the entire density of states energy range. However, it will be shown that this in no way limits the method.
               
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