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Effects of Pb doping on the electrical transport performance of Cu1.98Se

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Cu2−δSe is an eco-friendly thermoelectric candidate owing to Cu ions migration in its high-temperature beta phase, and meanwhile the liquid-like Cu ions deteriorate the stability and reliability of materials. Here,… Click to show full abstract

Cu2−δSe is an eco-friendly thermoelectric candidate owing to Cu ions migration in its high-temperature beta phase, and meanwhile the liquid-like Cu ions deteriorate the stability and reliability of materials. Here, Pb2+ ion was introduced into the Cu1.98Se lattice to improve the thermoelectric properties and the stability. The Pb-doped Cu1.98−xPbxSe (x = 0–0.035) compounds prepared by a facile solvothermal synthesis and microwave sintering. The obtained results reveal that the power factor of the doped samples greatly improved up to 1454 μW m−1 K−2 at 800 K, which was about 22.5% higher than that of undoped Cu1.98Se. In addition, after 3 cycles of testing, the power factor of Cu1.98Se decreased by 57% at 800 K, and that of Cu1.965Pb0.015Se decreased by less than 30%.

Keywords: electrical transport; performance cu1; effects doping; cu1 98se; doping electrical; transport performance

Journal Title: Journal of Materials Science
Year Published: 2019

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