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Monodispersed YF3:Ce3+/Tb3+/Eu3+ mesocrystals: hydrothermal synthesis and optical temperature sensing behavior

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In this work, uniform and monodispersed YF3:Ce3+/Tb3+/Eu3+ mesocrystals were successfully synthesized via a facile hydrothermal route for the first time. The results revealed that the as-obtained products belonged to orthorhombic… Click to show full abstract

In this work, uniform and monodispersed YF3:Ce3+/Tb3+/Eu3+ mesocrystals were successfully synthesized via a facile hydrothermal route for the first time. The results revealed that the as-obtained products belonged to orthorhombic system and exhibited hollow spindle $${\text{morphology}}$$morphology with an average size of 1.06 μm in length and 0.50 μm in width. The possible formation mechanism of hollow YF3 mesocrystals has been proposed. Moreover, the temperature-dependent luminescent properties of $${\text{Y}}{{\text{F}}_3}:{\text{C}}{{\text{e}}^{3 + }}/{\text{T}}{{\text{b}}^{3 + }}/{\text{E}}{{\text{u}}^{3 + }}$$YF3:Ce3+/Tb3+/Eu3+ mesocrystals are systemically investigated to explore the possible application of the presented sample in optical thermometry. As a consequence, the high sensitivity of 0.2% per K for $${\text{Y}}{{\text{F}}_3}:{\text{C}}{{\text{e}}^{3 + }}/{\text{T}}{{\text{b}}^{3 + }}/{\text{E}}{{\text{u}}^{3 + }}$$YF3:Ce3+/Tb3+/Eu3+ may make it quite promising candidate as optical thermometry. The study not only gives a reference for the synthesis of other rare earth fluorides mesocrystals, but also provides an significant advance in exploring other novel optical thermometry.

Keywords: tb3 eu3; text text; yf3 ce3; text; ce3 tb3

Journal Title: Journal of Materials Science: Materials in Electronics
Year Published: 2017

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