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Morphology control and magnetic properties of cauliflower-like CeO2 synthesized by a facile template-free hydrothermal method

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Cauliflower-like CeO2 particles composed of numerous nanorods with variable diameters of 100–220 nm have been successfully synthesized via a facile template-free hydrothermal method. The influences of the reaction time on the… Click to show full abstract

Cauliflower-like CeO2 particles composed of numerous nanorods with variable diameters of 100–220 nm have been successfully synthesized via a facile template-free hydrothermal method. The influences of the reaction time on the morphologies, crystal structures, and magnetic properties of the resulting products have been investigated. X-ray photoelectron spectroscopy shows that Ce4+ and Ce3+ ions coexist at the surface of the particles. M–H curve with the saturation magnetization (Ms) of 2.72 × 10− 2 emu/g, residual magnetization (Mr) of 0.58 × 10− 2 emu/g and coercivity (Hc) of 275 Oe, exhibits excellent room-temperature ferromagnetism, which is likely ascribed to their synergistic effect of the Ce3+ ions and oxygen vacancies.

Keywords: like ceo2; hydrothermal method; cauliflower like; facile template; free hydrothermal; template free

Journal Title: Journal of Materials Science: Materials in Electronics
Year Published: 2017

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