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Rietveld refinement and electrical properties of cadmium lithium phosphate

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Cadmium lithium phosphate, LiCdPO4, has been prepared by the solid state reaction method and characterized by X-ray powder diffraction at room temperature. This compound crystallizes in the orthorhombic system with… Click to show full abstract

Cadmium lithium phosphate, LiCdPO4, has been prepared by the solid state reaction method and characterized by X-ray powder diffraction at room temperature. This compound crystallizes in the orthorhombic system with Pnma space group. Vibrational study by means of Raman spectroscopy confirms the existence of the (PO4)3− functional group. The electrical properties have been investigated in the frequency range 209 Hz–1 MHz and temperature range 584–686 K. Experimental measurements of ac conductivity were fitted by the Jonscher’s universal power law: $${\sigma _{ac}}={\sigma _{dc}}+A{\omega ^n}.$$σac=σdc+Aωn.

Keywords: rietveld refinement; cadmium lithium; electrical properties; lithium phosphate

Journal Title: Journal of Materials Science: Materials in Electronics
Year Published: 2017

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