LAUSR

Environment friendly piezoelectric micro/nanogenerators have attracted tremendous attention due to the increasing demand of portable self-powered devices. Here, we report the synthesis of Bi0.5(Na0.6K0.4)0.5TiO3 (BNKT) ceramic via solid state reaction method and the fabrication of BNKT:PDMS based flexible energy harvester. The synthesized BNKT ceramic exhibits well-defined fatigue free P-E hysteresis loops up to 104 cycles favourable for high precision capacitors and sensors. A high value of piezoelectric charge coefficient (d33 = 154 pC N−1) was measured for BNKT ceramic, which indicates its potential application in flexible energy harvesting devices. A series of flexible BNKT:PDMS composite based microgenerators were fabricated with 10, 20, 30 and 40 wt% BNKT content and their dielectric and electrical properties were investigated. The energy harvester with 40 wt% BNKT achieved the highest dielectric constant and conductivity, whereas the device with 30 wt% BNKT ceramic generated the highest open circuit voltage of about 11 V under periodic compressive force of 20 N. These results imply that lead free BNKT:PDMS composite may be applied in pressure sensors and various energy harvesting devices.