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A new organic–inorganic hybrid compound contained bi-capped Bi Keggin anion, [biim][PMo1VMo11VIBi1.24O40]·3H2O (1) (biim = biimidazole) has been firstly synthesized and characterized by IR, UV–Vis, XRD, XPS, elemental analyses, fluorescent spectrum and TG… Click to show full abstract
A new organic–inorganic hybrid compound contained bi-capped Bi Keggin anion, [biim][PMo1VMo11VIBi1.24O40]·3H2O (1) (biim = biimidazole) has been firstly synthesized and characterized by IR, UV–Vis, XRD, XPS, elemental analyses, fluorescent spectrum and TG analysis. Compound 1 exhibits a novel 2-D supramolecular network structure constructed from {PMo1VMo11VIBi1.24O40} anions by O···O interactions, and further extends a 3-D supramolecular framework by bridges of biimidazole with N–H···O hydrogen bonding interactions. The compound 1 performs well catalytic property for epoxidation of styrene to styrene oxide. Moreover, compound 1 displays excellent photodegradation activity for methyl orange dye.
Journal Title: Journal of Cluster Science
Year Published: 2019
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